Either the first or second puzzle ever with more than 10,000 pieces. This debuted in 1978 and my (well-worn) copy is from a 1985 reprinting. This puzzle is exceptionally hard to find. (Update: It seems I am mistaken about there being a 1978 version of this. The 1985 printing is the original release; the first 12,000 piece puzzle Ravensburger released is definitively "The Temptation of St. Anthony" by Hieronymous Bosch, which debuted in 1983.)
Neuschwanstein Castle Germany at Eurographics
2015 Reflections / 2016 Resolutions, The BIG Jigsaw Puzzle Collection
EuroGraphics 5444 Neuschwanstein Castle Bavaria Germany Panoramic Puzzle (1000 Piece) : Toys & Games
White Mountain Puzzles Neuschwanstein Castle - 1000 Piece Jigsaw Puzzle, 144 months to 1188 months : Toys & Games
Vintage with 5000 & Up Pieces Jigsaw Puzzles for sale
3/4 SEALED RARE Ravensburger 12000 Neuschwanstein Castle Jigsaw Puzzle 1985
12000, Ravensburger, Neuschwanstein Castle - Rare Puzzles
RAVENSBURGER PUZZLE SUPER 200 Ritterburg Knight's Castle 1997 Made in France £8.62 - PicClick UK
RARE RAVENSBURGER 12000 PIECE JIGSAW PUZZLE NEUSCHWANSTEIN CASTLE, NIB SEALED
Landscapes Contemporary with 5000 & Up Pieces Jigsaw Puzzles for sale
RAVENSBURGER PUZZLE SUPER 200 Ritterburg Knight's Castle 1997 Made in France £8.62 - PicClick UK